1,4-Bis(3-chloropropoxy)benzene
نویسنده
چکیده
The mol-ecule of the title compound, C(12)H(16)Cl(2)O(2), has a center of inversion at the centroid of the benzene ring and the asymmetric unit contains one half-mol-ecule. Inter-molecular C-H⋯π inter-actions stabilize the crystal structure.
منابع مشابه
catena-Poly[[bis(2-aminoethanesulfonato-κ2 N,O)nickel(II)]-μ-1,4-bis(1H-imidazol-1-yl)benzene-κ2 N 3:N 3′]
In the hydro-thermally prepared title coordination polymer, [Ni(C(2)H(6)NO(3)S)(2)(C(12)H(10)N(4))](n), the Ni(II) ion and the 1,4-bis-(1H-imidazol-1-yl)benzene ligand occupy special positions on inversion centers. The metal ion shows a slightly distorted octa-hedral coordination geometry, being linked to two N atoms of two 1,4-bis-(imidazol-1-yl)benzene ligands and to two O and two N atoms of ...
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The title Cd(II) coordination polymer, catena-poly[[{1,4-bis-[1-(2-pyridylmeth-yl)benzimidazol-2-yl]butane}cadmium(II)]-μ-benzene-1,3-dicarboxyl-ato], [Cd(C(8)H(4)O(4))(C(30)H(28)N(6))](n), was obtained by reaction of CdCO(3), benzene-1,3-dicarboxylic acid (H(2)btc) and 1,4-bis-[1-(2-pyridylmeth-yl)benzimidazol-2-yl]butane (L). The Cd(II) cation is six-coordinated by an N(2)O(4)-donor set. L ac...
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Coordination polymers and a macrocycle formed from the reactions between flexible bis(2-pyridyl) ligands and AgCF(3)SO(3) are reported. The type of structure formed depends on the choice of ligand and the stoichiometry of the reaction. When 1 equiv of 1,4-bis(pyridin-2-ylmethoxy)benzene (L2), 4,4'-bis(pyridin-2-ylmethoxy)biphenyl (L4), or bis((4-pyridin-2-ylmethoxy)phenyl)methane (L5) is used, ...
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The crystallization of two dihydropyridyl molecules, 1,4-bis(4-(3,5-dicyano-2,6-dipyridyl)dihydropyridyl)benzene ([C40H24N10]·2DMF, 1·2DMF; DMF = dimethylformamide) and 1,4-bis(4-(3,5-dicyano-2,6-dipyridyl)dihydropyridyl)phenylbenzene ([C46H28N10]·2DMF, 3·2DMF), and their respective oxidized pyridyl analogues, 1,4-bis(4-(3,5-dicyano-2,6-dipyridyl)pyridyl)benzene ([C40H20N10], 2) and 1,4-bis(4-(...
متن کاملSynthesis of a diamino substituted terphenyldivinyl chromophore.
(E,E)-1,4-bis(4'-aminostyryl)-2,5-bis(octyloxy)-benzene (6) and its derivative (E,E)-1,4-bis(4'-acetamidostyryl)-2,5-bis(octyloxy)-benzene (7) were synthesized and characterized after alkylation, bromomethylation, Horner-Emmons reaction and reduction from hydroquinone. In order to gain more molecular electronic data, HOMO and LUMO of compound 6 have been calculated by Gaussian 03 W.
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2010